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I've only done shrooms and always had a great trip, but let me warn you of three things that happened to me:
1) DO NOT be with somebody that will overwhelm you with talking/questions, don't understand the trip, or anything like that. I had a friend with me my first time taking an eighth of shrooms and he turned my trip bad. He just kept talking and didn't understand what I was going through or feeling so he thought it was a big joke. I wanted to beat the shit out of him for it because it messed up at least half of my trip.
2) I recommend having at least a dub, preferably an eighth of weed on you to smoke because it helps settle your body and decreases a chance of a bad trip or a bad comedown.
3) The comedown - the worst part of the shrooms. I didn't have any weed my first two times taking shrooms, and the comedown was horrible. I felt really depressed and although I knew I still had a lot of goals in life that I wanted to achieve, they seemed like nothing. Like why should I keep working hard at things if we're all going to die someday... things like that.
Seeing as I've never taken a hit of acid, I can't tell you which one is better. I will say that you wouldn't trip as hard from an eighth of shrooms than you would a hit of good acid, so I'd be guessing shrooms are the way to go first time. As a tip for eating the shrooms, I say grind it up as much as you can and put it in a glass of orange juice with tons of pulp. You can't taste them hardly and the trip hits you in about 15-20 minutes as opposed to 30-60 minutes.
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