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^Way I look at it if your going to work work fucking hard, and!...make sure that the hours your putting in ultimately benefit YOURSELF more then anybody else. Seem selfish? Don't know what to tell ya. That's Business? Too cliche...oh well.
Anyway...going into business for yourself in anything, even just cutting lawns or selling door to door, is a GREAT asset to ANYBODY'S resume' and skill set. Learning the very foundation and basics that go into running a day to day business is priceless. You will understand the struggles and necessities that go through the minds of people that run companies. You will learn how to sell yourself to them by actually developing business strategy!

But...until you got money to start, work for the company that pay's highest and has the highest probability of getting noticed and promoted (or people to just know).